Matched pair Student's t-test

#1
Hi All,
I did estimation of a compound in different samples (10 samples) by two methods with triplicate. How can I compare these results to find out which method is superior, in literature they used Matched pair Student's t-test but in my experiment the mean of each sample are different;
for eg:
.............. Method 1 ..........Method 2
Sample 1.....120...................123
Sample 2.......10 ...................11
Sample 2.......77....................78

etc

Please suggest a method to solve this problem

Thanks in advance