Scheffe is not accepted by most researchers these days. It's very conservative, meaning signficant effects won't be detected. SPSS does not do it the way it was actually intended either.
The problem with interpreting main effect when you have interaction is that main effects impact on the dependent variable will vary at different levels of the second main effect.
For example, say you have an independent variable with three levels and it interacted with a 2nd indendent variable with two levels. Then level one of the first independent variable might be lower on the dependent variable than that (independent) variable level three - at level one of the 2nd independent variab le. But at level two of the second independent variable level one of the first independent variable might be higher on the dependent variable than the first independent variable's level three.
So you can only interpret main effects at specific level of the other independent variable - not globally.